Why is the play/stop button on the player disabled (grayed out)?
StreamS | Support | How-to Manual

The play/stop button is disabled when the station is not yet loaded into the player. StreamS automatically loads the last played station into the player. If you run StreamS for the first time, there will be no station loaded into the player yet. Simply browse for stations in the "Stations" tab or click here to find more ways to load a station into the player.